A Physico-chemical Study on the Hydrolysis of Thorium Nitrate
- 1 March 1955
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 28 (3) , 162-164
- https://doi.org/10.1246/bcsj.28.162
Abstract
1) The dilution effect on the pH change in a dilute solution and in the presence of sodium perchlorate was followed by a glass electrode. 2) A linear relationship is held between pH and −logC. The curves plotting pH vs. −logC run parallel with each other at varying ionic strengths, and the slope is nearly equal to 1/2 by which the most possible existence of Th(OH)+3 is pressumed. 3) The equilibrium constants for ion species, ThOH+3 and Th(OH)2+2, are calculated stoichiometrically from the data of hydronium ion concentration observed and the total concentration of thorium nitrate.This publication has 4 references indexed in Scilit:
- Electrolytic Behavior of Elements of the Group VIa in the Periodic System. I. Potentiometric Studies on the Chromate, Molybdate and Tungstate IonsBulletin of the Chemical Society of Japan, 1953
- The Hydrolysis and Polymerization of Zirconium in Perchloric Acid Solution1Journal of the American Chemical Society, 1951
- The Aqueous Chemistry of ZirconiumJournal of the American Chemical Society, 1949
- Thorium in Monazite SandAnalytical Chemistry, 1948