Dynamics of charge transfer and chemical reactions of doubly-charged ions at low collision energies
- 1 March 1996
- journal article
- research article
- Published by Taylor & Francis in International Reviews in Physical Chemistry
- Vol. 15 (1) , 299-324
- https://doi.org/10.1080/01442359609353186
Abstract
Results of beam scattering studies on the dynamics of single charge transfer and chemical reactions of doubly-charged ions carried out in Prague are reviewed. Investigation of several atomic ion-atom charge transfer processes at collision energies 0·1-10 eV provides data on differential and relative total cross-sections of state-to-state processes. Populations of electronic and vibrational states of molecular product ions are obtained from experiments on molecular dication-atom and atomic ion (He2+)-molecule systems. Studies of chemical reactions of the dication CF2+ 2 with D2 show that Coulomb repulsion between the products (CF2D+ + D+) governs the dynamics and energy partitioning.Keywords
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