The NMR spectrum of pentafluorothiophenol
- 1 August 1969
- journal article
- research article
- Published by Wiley in Magnetic Resonance in Chemistry
- Vol. 1 (4) , 295-303
- https://doi.org/10.1002/mrc.1270010403
Abstract
High‐precision line measurements and tickling were shown to yield information, often not accessible, on the assignment and signs of spin coupling constants. For pentafluorothiophenol‐d, this information was obtained for the three meta‐JFF's. Relative to C6F5SH, the 19F resonances in C6F5SD experienced an upfield ‘isotope’ shift.Keywords
This publication has 16 references indexed in Scilit:
- Application of Low-Field NMR to the Un-ambiguous Assignment of Spin-Coupling Parameters. II. Determination of the Relative Signs of JFFo and JHFo from the 1H Spectrum of PentafluorobenzeneThe Journal of Chemical Physics, 1969
- NMR Subspectral Analysis Applied to Polyfluorobenzenes C6HnF6−n. III. PentafluorobenzeneThe Journal of Chemical Physics, 1968
- NMR Subspectral Analysis Applied to Polyfluorobenzenes C6HnF6–n. II. 1,2,3,4-TetrafluorobenzeneThe Journal of Chemical Physics, 1968
- Nuclear magnetic resonance spectra of fluorobenzenes. II. Effect of substituents on the meta and para fluorine-fluorine coupling constantsJournal of the American Chemical Society, 1968
- Fluorine-19 nuclear magnetic resonance studies on some polyfluroaromatic compounds and their metal complexesJ. Chem. Soc. A, 1968
- Fluorine nuclear magnetic resonance spectra of some polyfluoroaromatic compoundsJournal of the Chemical Society B: Physical Organic, 1968
- Alternative Representation of Energy Level Diagrams for NMR SpectraThe Journal of Chemical Physics, 1967
- Analysis of AA'BB' nuclear magnetic resonance spectra by weak double irradiation. Application of two isomeric cyclobutane derivativesJournal of the American Chemical Society, 1967
- Application of Low-Field NMR to the Unambiguous Assignment of Spin-Coupling Parameters. I. Pentafluoro-IodobenzeneThe Journal of Chemical Physics, 1967
- Fluorine-19 Nuclear Magnetic Resonance Studies of ι Interactions in Pentafluorophenylphosphines and Their Complexes. A Correlation of Coupling Constants with Chemical ShiftsJournal of the American Chemical Society, 1966