ON THE INTERACTION BETWEEN DIALKYL PHOSPHITES AND AMINE HYDROCHLORIDES

1 October 1981

journal article
research article
Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements

Vol. 11 (3) , 363-367
https://doi.org/10.1080/03086648108077436

Abstract

The interaction between dialkyl phosphites and amine hydrochlorides is examined. It is found that an alkyl halide is evolved and an ammonium monoalkyl phosphonate, i.e. (R)₃NH⁺O⁻P(H)(O)(OR), is formed.

Keywords

AMMONIUM
AMINE
PHOSPHONATE
PHOSPHITES
HALIDE
DIALKYL
3NH
MONOALKYL
HYDROCHLORIDES

This publication has 3 references indexed in Scilit:

Reactivity of Trivalent Phosphorus Derivatives
Russian Chemical Reviews, 1970
Conversion of Tertiary Phosphites to Secondary Phosphonates. Diphenyl Phosphonate¹
Journal of the American Chemical Society, 1959
Dealkylation of Diisopropyl Phosphite by Hydrogen Chloride1
Journal of the American Chemical Society, 1955