Coexistence in dipolar fluids in a field
- 6 June 1994
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 72 (23) , 3686-3689
- https://doi.org/10.1103/physrevlett.72.3686
Abstract
We examine two phase coexistence for soft sphere dipolar fluids in an applied field, H. Besides being a fundamental test system for theory, dipolar fluids are used as models for ferrofluids. Gibbs ensemble simulations were performed to determine the coexistence curve and an estimate of the critical temperature, , and density, , as a function of applied magnetic field. In zero field we show that coexistence most likely does not occur and if it does can only do so in a narrow range of densities much lower than predicted theoretically. We discuss the structure of soft sphere dipolar systems, which turns out to be much more complex than previously thought.
Keywords
This publication has 22 references indexed in Scilit:
- Global phase diagrams for dipolar fluidsPhysical Review E, 1994
- Electrorheological FluidsScientific American, 1993
- The third dielectric and pressure virial coefficients of dipolar hard sphere fluidsMolecular Physics, 1993
- Equilibrium properties of ferrocolloidsPhysica A: Statistical Mechanics and its Applications, 1992
- Statistical thermodynamics of ferrofluidsPhysica A: Statistical Mechanics and its Applications, 1992
- Magnetic properties of ferrocolloids: The effect of interparticle interactionsJournal of Magnetism and Magnetic Materials, 1987
- Chain formation in magnetic fluid compositesIEEE Transactions on Magnetics, 1986
- Theory of Agglomeration of Ferromagnetic Particles in Magnetic FluidsJournal of the Physics Society Japan, 1983
- Magnetic FluidsScientific American, 1982
- Theory of polar liquidsMolecular Physics, 1973