Chemical Properties of Cometary Dust and A Note on Carbon Isotopes

Abstract
On board the space probes Giotto and VEGAs and 2, which were sent through the coma of comet Halley, were the mass spectrometers PIA and PUMAs 1 and 2 for the in situ analysis of cometary dust. This paper summarizes the results obtained up to now, about four years after the flybys. It is sought to make the reader aware of the significance, but also of the limitations, of these unprecedented data gathered within a few hundred seconds with an innovative instrument about 1.5 x 108 km away from Earth. The first part of this paper shows how the bulk properties of the dust are derived—the main constituents CHON and silicates, the core-mantle structure, the molecular composition of the organic component, the average composition of the dust and of the whole comet, and the gas/dust ratio. The second part reviews what can safely be said about the properties of the individual grains—their similarity to a certain class of interplanetary dust particles and their distinction from others, and their density and masses. The final part of this paper shows that some cometary grains contain isotopically ultra-light carbon (12C/13C up to 5000), a finding that is significantly substantiated by reports of similar carbon isotopic composition in meteoritic graphite.