First examples of η1-ligated 1,2,4-triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C2R2P3)(PEt3)2], (R = But, adamantyl), (M = Pd, Pt); crystal and molecular structures of trans-[PtX(C2But2P3)(PR3)2], (X = Cl, R = Et; X = I, R = Ph)
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1615-1617
- https://doi.org/10.1039/c39880001615
Abstract
First examples of η1-ligated 1,2,4-triphosphacyclopentadienyl ring systems are described and structural features and solution fluxional behaviour are discussed.Keywords
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