Raman spectra of aliphatic chlorine compounds: II. Chloroethenes and chloropropenes
- 1 January 1955
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 74 (8) , 957-975
- https://doi.org/10.1002/recl.19550740805
Abstract
Complete Raman spectra, inclusive of depolarization factors, are given for sixteen out of the thirty‐one possible chlorine derivatives of propene, ten of which have been prepared especially for this purpose.Examination of the Raman results shows that the “specific group frequencies” derived for groups such as CH2, CH2Cl, CHCl2, and CCl3 from the Raman spectra of chloroethanes and chloropropanes largely retain their values in the chloropropenes.From a comparative study of the Raman spectra of chloroethenes and ‐propenes an additional number of specific group frequencies is deduced, characterizing the configurations CH2, CH, CHCl, and CCl2.The carboncarbon double‐bond frequency proper shows a decreasing value with an increasing degree of substitution of chlorine for hydrogen in the molecule.Keywords
This publication has 14 references indexed in Scilit:
- Raman spectra of aliphatic chlorine compounds: I. Chloroethanes and chloropropanesRecueil des Travaux Chimiques des Pays-Bas, 1955
- The infra-red and Raman spectra of hydrocarbons. Part II. ParaffinsQuarterly Reviews, Chemical Society, 1953
- Allylic Chlorides. XV. Preparation and Properties of the 1,2,3-Trichloropropenes1Journal of the American Chemical Society, 1952
- The Dipole Moments of the Isomeric Dichloropropenes1Journal of the American Chemical Society, 1950
- THE CONFIGURATION OF THE 1,3-DICHLOROPROPENESJournal of the American Chemical Society, 1949
- Preparation of 1,2-Dichloropropene-1Journal of the American Chemical Society, 1948
- Discussion of the structure of a few polychloro compounds with the help of raman effect dataRecueil des Travaux Chimiques des Pays-Bas, 1947
- The Preparation and Directed Chlorination of 1,1,1-TrifluoropropaneJournal of the American Chemical Society, 1942
- Chlorinated Derivatives of 2-FluoropropaneJournal of the American Chemical Society, 1941
- A quantum mechanical discussion of the dipole moments of monochlorobenzene and of vinylchlorideRecueil des Travaux Chimiques des Pays-Bas, 1939