Separation of Boron Isotopes. IV. The Methyl Sulfide-BF3 System
- 1 September 1960
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 33 (3) , 779-781
- https://doi.org/10.1063/1.1731260
Abstract
The exchange of boron between BF3 (gas) and the dimethyl sulfide‐BF3 complex (liq.) was studied from —20°C to +26°C. The single stage separation factor changed from 1.056 to 1.031 over this temperature range with B10 concentrating in the liquid phase. Vapor pressures of dimethyl sulfide and of various mixtures of BF3 and dimethyl sulfide were determined. ΔH for the reaction BF3 (gas)+Me2S (liq.)→BF3·Me2S (liq.) was estimated to be —10.1 kcal/mole over the above temperature range. The melting point of the 1:1 complex was —19.6°C.Keywords
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