[MoR(η3‐C3H5)3], R = Alkyl: Alkylmolybdenum Complexes with Agostic C-H ⇀ Mo Bond
- 1 June 1986
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 25 (6) , 555-556
- https://doi.org/10.1002/anie.198605551
Abstract
A dramatic high‐field shift of an 1H‐NMR signal characterizes the agostic Mo↼HC interaction in the isopropylmolybdenum complex 2. The bright yellow compound is accessible in 65% yield by reaction of the binuclear molybdenum complex 1 with isopropylmagnesium chloride at −78°C in ether. equation imageKeywords
This publication has 4 references indexed in Scilit:
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- Implications of three-center, two-electron M--H--C bonding for related alkyl migration reactions: design and study of an ethylene polymerization catalystJournal of the American Chemical Society, 1985
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- Carbonhydrogen-transition metal bondsJournal of Organometallic Chemistry, 1983