Manganese carbonyl–diaza-allyl complexes. Mn–N bond formation by decarbonylation of carbamoyl-type complexes
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 774-775
- https://doi.org/10.1039/c39720000774
Abstract
The cyclic carbamoyl complexes [(CO)4-[graphic omitted]R2] undergo both thermal and photochemical decarbonylation to form novel π-diazaallyl complexes (CO)4[graphic omitted]R2; attempts to reverse the process by treatment with CO at high pressures and temperatures gave only [(CO)5MnN(R2)C(R1):NR2]; no evidence was obtained for insertion into the Mn–N bonds.Keywords
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