Addition of MeMgSnBun 3 to terminal enyne; preparation of geometrically pure 2-substituted 1-lodo-1,3-dienes
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1438-1439
- https://doi.org/10.1039/c39930001438
Abstract
The title iododienes have been prepared from 6-phenylhex-3-en-yne by the addition of methylmagnesiumtributyltin, followed by reactions of stannylmagnesium intermediate Awith appropriate electrophiles and of the resulting alkylated stannylidiene Bwith iodine.Keywords
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