Partial molal volumes of some halobenzenes in carbon tetrachloride
- 1 July 1983
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 61 (7) , 1414-1416
- https://doi.org/10.1139/v83-247
Abstract
The partial molal volumes at infinite dilution for a number of halobenzenes are measured and related to their van der Waals volumes. Results indicate larger volume increments for halogen atoms in halobenzenes than those in alkyl halides. Possible explanations are forwarded. The effect of steric overcrowding in ortho-substituted benzenes on the values are evaluated.Keywords
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