Cation-controlled formation of [{MCl4}n]2n− chains in [4,4′-H2bipy][MCl4] (M = Mn, Cd): an alternative to the A2MCl4 layer perovskite structure†
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 22,p. 2287-2288
- https://doi.org/10.1039/a907681f
Abstract
The cis-MCl2‥HN+ chelated hydrogen bond synthon has been exploited in preparation of crystalline [4,4′- H2bipy][MCl4] (M = Mn 2 and Cd 3), which shows a one-dimensional substructure of the form [{MCl4}n]2n– consisting of a kinked chain of doubly edge sharing MCl6 octahedra. These chains are cross-linked by hydrogen bonding to the [4,4′-H2bipy]2+ ions.Keywords
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