Nucleophilic Aromatic Substitution Reactions of 1-Methoxy-2-(diphenylphosphinyl)naphthalene withC-,N-, andO-Nucleophiles: Facile Synthesis of Diphenyl(1-substituted-2-naphthyl)phosphines
- 1 January 1994
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1994 (02) , 199-202
- https://doi.org/10.1055/s-1994-25438
Abstract
A novel nucleophilic aromatic substitution reaction is described in which the methoxy group of 1-methoxy-2-(diphenylphosphinyl)-naphthalene is readily replaced with Grignard reagents, alkoxides, and amides. Reduction of the resulting phosphine oxides provides a convenient route to diphenyl(1-substituted-2-naphthyl)phosphines.Keywords
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