Ferrocenylen-cobaltocenylenium-hexafluorophosphat [(h5:h5'-C10H8)2FeCo] [PF6], ein gemischtkerniger Komplex vom Bis(fulvalen)dimetall-Typus / Ferrocenylenecobaltocenyleniumhexafluorophosphate [(h5:h5'-C10H8)2FeCo] [PF6], a Mixed Membered Complex of Bisfulvalenedimetal Type
Open Access
- 1 November 1983
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 38 (11) , 1493-1496
- https://doi.org/10.1515/znb-1983-1128
Abstract
Ferrocenylenecobaltocenylenium-monochloride and ferrocenylenecobaltocenylenium-hexafluorophosphate were prepared under the aspect of influencing the valence averaging phenomena described for homodinuclear metallofulvalenes. Detected paramagnetism of the monocation is assumed to result from such interactions in dibridged rigid metallocenes. The above cation is characterized by IR, CV, MS, electron microprobe and elemental analyses.Keywords
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