Direct observation of enantiomeric rotational isomers using 1H nuclear magnetic resonance spectroscopy
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 537-539
- https://doi.org/10.1039/c39730000537
Abstract
The existence of enantiomeric rotational isomers in solutions of certain 5-oxidovinylphenanthridiniums and other sterically hindered molecules has been demonstrated by 1H n.m.r. spectroscopy using tris-[3-(trifluoromethylhydroxymethylene)-(+)-camphorato]europium(III).Keywords
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