Cation radicals of phenothiazines. Part 4. Electron transfer between aquamanganese(III) and N-alkylphenothiazines
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 3,p. 484-486
- https://doi.org/10.1039/dt9800000484
Abstract
The kinetics of electron transfer between aquamanganese(III) and N-alkylphenothiazines, giving rise to the corresponding cation radicals, has been investigated in the range 0.20–1.50 mol dm–3 HClO4 at different temperatures. The main reaction path has been assigned to the unhydrolysed species Mn3+(aq), and there is a dependence of the rate constants on the corresponding reduction potentials.Keywords
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