Solvent participation in catalytic trans-hydrogenation of an olefinic double bond
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 234-235
- https://doi.org/10.1039/c39730000234
Abstract
trans-Addition in the palladium-catalysed hydrogenation of dimethyl bicyclo[2,2,2]oct-2-ene-2,3-dicarboxylate (1) increased from 1 to over 60% if traces of strong acid were present; as shown by deuteriation experiments, the solvent participates in the formation of the trans-isomer.Keywords
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