Excitonic Funneling in Extended Dendrimers with Nonlinear and Random Potentials

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Abstract
The mean first passage time (MFPT) for photoexcitations diffusion in a funneling potential of artificial treelike light-harvesting antennas (phenylacetylene dendrimers with generation-dependent segment lengths) is computed. Effects of the nonlinearity of the realistic funneling potential and slow random solvent fluctuations considerably slow down the center-bound diffusion beyond a temperature-dependent optimal size. Diffusion on a disordered Cayley tree with a linear potential is investigated analytically. At low temperatures we predict a phase in which the MFPT is dominated by a few paths.
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