Synthesis and characterization of thiovanadyl (VS2+) complexes
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 75-76
- https://doi.org/10.1039/c39800000075
Abstract
The existence of the thiovanadyl ion, VS2+, has been established by reaction of VO(salen) and VO(acen)[H2salen =NN′-ethylenebis(salicylideneamine); H2acen =NN′-ethylenebis(acetylacetonylideneamine)] with B2S3 to form the thiovanadyl compounds; infrared and e.s.r. spectroscopy indicate that the VS bond has greater covalency but is weaker than its vanadyl analogues.Keywords
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