An enneanuclear nickel sulphide with a confacial bi-octahedral geometry. X-Ray crystal structure of [Ni9(µ4-S)3(µ3-S)6(PEt3)6][BPh4]2
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 47-48
- https://doi.org/10.1039/c39810000047
Abstract
An X-ray analysis of [Ni9S9(PEt3)6][BPh4]2 shows that the nine nickel atoms in the [Ni9S9(PEt3)6]2+ cluster lie in a confacial bi-octahedral arrangement and are held together by bridging sulphur atoms, while six phosphine groups complete the co-ordination around the nickel atoms.Keywords
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