Preparation and characterization of the first isothiazolyl and isothiazolinylidene complexes of gold (I)
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 2067-2071
- https://doi.org/10.1039/dt9950002067
Abstract
Isothiazolyl complexes have been synthesized by the addition of isothiazol-5-yllithium to gold(I) chloride or tetrahydrothiophene(pentafluorophenyl)gold complexes. Protonation or alkylation of these isothiazolyl complexes yielded the corresponding isothiazolinylidene complexes. The mono(isothiazolyl)-aurate and mono(isothiazolinylidene) complexes undergo homoleptic rearrangement. The molecular structure of the mono(isothiazolyl)complex [Au[graphic omitted](PPh3)] shows a gold–carbon bond length of 2.032(7)Å.Keywords
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