Stereoselective Synthesis of Allyl- or Alkynyl-Substituted (Z)-Vinylsilanes via Organoboranes
- 1 February 1986
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 59 (2) , 659-660
- https://doi.org/10.1246/bcsj.59.659
Abstract
Copper(I) iodide-catalyzed cross-coupling reactions of (Z)-(1-trimethylsilyl-1-alkenyl)dicyclohexylboranes with allyl bromide or 1-bromo-1-hexyne gave stereoselectively (Z)-1,4-dienes or conjugated (Z)-enynes having a trimethylsilyl group on the internal carbon atom of the double bond.This publication has 4 references indexed in Scilit:
- Bis(acetylacetonato)copper Catalyzed Cross-coupling Reaction of Alkenyldicyclohexylborane with 1-Bromo-1-alkyne or 3-Bromo-1-propeneBulletin of the Chemical Society of Japan, 1983
- Stereospecific synthesis of symmetrical conjugated dienes with alkenylcopper intermediates from alkenyldialkylboranesThe Journal of Organic Chemistry, 1980
- Novel syntheses of monosubstituted acetic, .alpha.,.beta.-unsaturated, and .beta.,.gamma.-unsaturated acids via silylation, hydroboration, and oxidation of the ethynyl group of 1-alkynes and functionally substituted 1-alkynesJournal of the American Chemical Society, 1977
- Stereoselective synthesis of vinylsilanes from alkynylsilanes by reductive alkylation via hydroboration, transmetallation and carbodemetallationTetrahedron, 1977