On Moment Conserving Decoupling Techniques for Electron Propagators

Publisher Website
Google Scholar
Abstract
Moment‐conserving decoupling procedures for the one‐electron Green's function (electron propagator) are investigated. By analysis of one particular system (Hubbard model) it becomes clear that the moment‐conserving techniques so far proposed for interacting systems are all special cases of [1, 0], [2, 1], or [3, 2] Padé approximants differing only in which terms they omit, how they define self‐consistency, and which operator algebra they utilize. The number of formally conserved moments appears not to be a particularly useful criterion of the accuracy of a decoupling procedure, since a two‐moment scheme (Hartree‐Fock) may be numerically closer to the exact answer than some three‐moment procedures. Use of the complete Padé approximant, as suggested by Lukman and Goscinski for the particle‐hole propagator, appears to be the most consistent method.

This publication has 15 references indexed in Scilit: