Exchange perturbation theories
- 1 September 1987
- journal article
- research article
- Published by Wiley in International Journal of Quantum Chemistry
- Vol. 32 (3) , 377-396
- https://doi.org/10.1002/qua.560320307
Abstract
Various earlier‐proposed perturbative approaches to the description of weakly interacting species are considered. It is argued that most of these perturbative approaches, including many of the so‐called exchange perturbation theories, exhibit a number of difficulties and limitations, which have not previously been emphasized. From these criticisms positive suggestions as to the nature of a general exchange perturbation‐like theory are made. Finally, a candidate for such a theory is outlined.Keywords
This publication has 48 references indexed in Scilit:
- The ‘‘primitive’’ wave function in the theory of intermolecular interactionsThe Journal of Chemical Physics, 1980
- Many-electron exchange Hamiltonian in the theory of ferromagnetismJournal of Magnetism and Magnetic Materials, 1977
- Electronic structure of Mott insulatorsAdvances in Physics, 1977
- The convergence of the Rayleigh-Ritz Method in quantum chemistryTheoretical Chemistry Accounts, 1977
- The relationship between the Rayleigh‐Schrödinger and asymptotic perturbation theories of intermolecular forcesInternational Journal of Quantum Chemistry, 1976
- Perturbation theories for the calculation of molecular interaction energies. I. General formalismThe Journal of Chemical Physics, 1973
- Theory of intermolecular forces. I. On the inadequacy of the usual Rayleigh‐Schrödinger perturbation method for the treatment of intermolecular forcesInternational Journal of Quantum Chemistry, 1971
- Approximate Wave Functions for Molecules and Crystals Using Perturbation TheoryReviews of Modern Physics, 1967
- The Representation of Long Range Forces by Series Expansions I: The Divergence of the Series II: The Complete Perturbation Calculation of Long Range ForcesProceedings of the Physical Society. Section A, 1956
- Über das Verhältnis der van der Waalsschen Kräfte zu den homöopolaren BindungskräftenThe European Physical Journal A, 1930