Application of indium ate complexes to synthetic chemistry. Selective conjugate addition to enones and coupling with allylic halides
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 824-825
- https://doi.org/10.1039/c39910000824
Abstract
Tetraorganoindium ate complexes, prepared by the addition of organolithium reagents to trialkylindium, reacted with α,β-unsaturated ketones in a 1,4-addition fashion; allylic indates derived from allylic indium sesquihalides coupled with allylic halides regio- and stereo-specifically to give high yields of head-to-tail 1,5-dienes.Keywords
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