Preparation and X-ray crystal structure of iodocycloheptasulphur hexafluorantimonate(VI), [S7I]+[SbF6]?

Abstract
The salts [SxI]+[MF6](x= 7 or possibly 8, M = As or Sb) have been prepared by various reactions; the crystal structure of [S7I]+[SbF6] shows the cation to contain iodine bonded to a sulphur atom of a seven-membered sulphur ring.

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