Alkylidene–Dithiocarbamate coupling—crystal structure of [Ru{κ2-CH(C6H4OMe-4)SC(NC4H8)S}{κ2-S2CNC4H8}(CO)(PPh3)]
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in New Journal of Chemistry
- Vol. 22 (4) , 311-314
- https://doi.org/10.1039/a801542b
Abstract
The reaction of [Ru(â–·CC6H4OMe-4)Cl(CO)(PPh3)2] with [NH4][S2CNC4H8] provides the structurally characterised metallacycle [Ru{κ2-CH(C6H4OMe-4)SC(NC4H8)S}(S2CNC4H8)(CO)(PPh3)], related examples of which arise from the reactions of xanthate or dithiocarbamate salts with the alkylidene compounds [MCl2(CHR)- (CO)(PPh3)2] (M=Ru or Os; R=Ph or C6H4OMe-4) and [OsCl(CHR)(OH2)(CO)(PPh3)2]ClO4.Keywords
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