Novel Initiators Having Acetylene Group for Polymerization of 2-Oxazolines
- 1 October 1991
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 20 (10) , 1771-1774
- https://doi.org/10.1246/cl.1991.1771
Abstract
Propagylic halide type compounds such as propagyl bromide, 1,4-dibromo-2-butyne, and 1,6-dibromo-2,4-hexadiyne, were used for the polymerization of 2-oxazolines. The polymerization initiated by these initiators gave polymers with narrow molecular weight distribution. From kinetic study, the polymerization using these initiators is found to be a relatively fast initiation system.This publication has 6 references indexed in Scilit:
- Surface properties and abhesion of undecyl oxazoline block and homopolymersJournal of Polymer Science Part B: Polymer Physics, 1991
- Novel covalent-type electrophilic polymerization of 2-(perfluoroalkyl)-2-oxazolines initiated by sulfonatesMacromolecules, 1991
- Synthesis of poly(2-oxazoline) macromonomers having a vinyl ester groupMacromolecules, 1991
- Ethylenimine polymersProgress in Polymer Science, 1990
- Novel bifunctional initiator for polymerization of 2-oxazolines via fast initiationMacromolecules, 1990
- Synthesis and characterization of a multiblock copolymer of poly(N‐isovaleryl ethyleneimine) and poly(ethylene glycol)Journal of Polymer Science Part A: Polymer Chemistry, 1988