The first unambiguous determination of a nitrosyl-to-nitrite conversion in an iron nitrosyl porphyrin
- 8 November 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 23,p. 2301-2302
- https://doi.org/10.1039/b006775j
Abstract
The picket fence porphyrin complex [Fe(tpivpp)(NO)] undergoes complete conversion to the isolable N-bound nitrite derivative [Fe(tpivpp)(NO2)(py)] in air in the presence of pyridine: reconversion to the starting nitrosyl complex is achieved using triphenylphosphine as reductant.Keywords
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