Carbonium-ion photochemistry: the benzenonium–bicyclo[3,1,0]hexenyl cation photoisomerisation
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 22,p. 1540-1541
- https://doi.org/10.1039/c29700001540
Abstract
The photochemical conversion of protonated durene in fluorosulphuric acid into a bicyclo[3,1,0]hexenyl cation has been shown to proceed by a symmetry-allowed distrotatory closure rather than by a [σ2a+π2a]cycloaddition reaction.Keywords
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