Integrated infrared intensities and atomic polar tensors in fluoroform
- 1 December 1980
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 73 (11) , 5591-5597
- https://doi.org/10.1063/1.440079
Abstract
The integrated intensities of the fundamental modes in HCF3 and DCF3 have been measured by Wilson–Wells–Penner–Weber method, and the atomic polar tensors were derived. The effective atomic charge for fluorine was found to be χF/e=0.598±0.018, in good agreement with that in other fluorocarbons. The effective atomic charge for hydrogen was found to be χH/e=0.049±0.006, a value somewhat lower than that found in other hydrocarbons and their derivatives.Keywords
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