Kinetic effects of fluorine substituents in free-radical chemistry. Hydrogen-atom abstraction reactions of perfluoro-n-alkyl radicals
- 30 June 1995
- journal article
- Published by Elsevier in Journal of Fluorine Chemistry
- Vol. 72 (2) , 235-240
- https://doi.org/10.1016/0022-1139(94)00413-a
Abstract
No abstract availableKeywords
This publication has 16 references indexed in Scilit:
- Absolute rate constants for some reactions of perfluoro-n-alkyl radicals in solutionJournal of the American Chemical Society, 1994
- Competition Methods and Scales for Alkyl Radical Reaction KineticsTetrahedron, 1993
- Alkene reactivities toward a strongly electrophilic radical. First absolute rate constants for some reactions of perfluoro-n-alkyl radicals in solutionJournal of the American Chemical Society, 1993
- A comment on the use of triethylsilane as a radical-based reducing agentThe Journal of Organic Chemistry, 1993
- Rate constants and Arrhenius parameters for the reactions of some carbon-centered radicals with tris(trimethylsilyl)silaneThe Journal of Organic Chemistry, 1991
- Absolute electronegativity and hardness: applications to organic chemistryThe Journal of Organic Chemistry, 1989
- Pentamethyldisilyl radical: absolute rate constants for its formation and for some halogen abstraction and addition reactionsThe Journal of Organic Chemistry, 1986
- Hydrocarbon Bond Dissociation EnergiesAnnual Review of Physical Chemistry, 1982
- Rate constants and Arrhenius parameters for the reactions of primary, secondary, and tertiary alkyl radicals with tri-n-butyltin hydrideJournal of the American Chemical Society, 1981
- Nucleophilic character of the alkyl radicals. 16. Absolute rate constants and the reactivity-selectivity relationship in the homolytic aromatic alkylationJournal of the American Chemical Society, 1977