Analysis of Eu2+ Spin-Hamiltonian Parameters
Open Access
- 1 January 1976
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Physics
- Vol. 29 (4) , 263-272
- https://doi.org/10.1071/ph760263
Abstract
The superposition model is used to determine single-ligand spin-Hamiltonian parameters for Eu2+ in a range of host crystals. The properties of these parameters are shown to be generally similar to those of the corresponding parameters for Gd3+, although some striking differences occur in their relative magnitudes and distance dependence. Both the similarities and the differences confirm aspects of a previous interpretation of the spin-Hamiltonian parameters for f7 8S7/2 ground states.Keywords
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