Some new amide complexes of thorium tetrachloride and N-thiocyanate
- 1 April 1983
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 61 (4) , 708-711
- https://doi.org/10.1139/v83-131
Abstract
The amide complexes [ThCl4L3], where L = CH3CON(CH3)2 (dma), C2H5CON(CH3)2 (dmpa), C2H5CON(C2H5)2 (depa), or (CH3)3CCON(CH3)2 (dmpva), [Th(NCS)4L4], where L = dmpa, depa, dmiba ((CH3)2CHCON(CH3)2), or dmpva, and [Th(NCS)4 (dmpva)3] have been prepared and their ir spectra reported. The observations are discussed in terms of the steric crowding about the thorium atom using a cone-packing model.Keywords
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