Hydrothermal synthesis of two-dimensional organic–inorganic hybrid materials of the nickel–molybdate family: the structures of [{Ni(3,3′-bpy)2}2Mo4O14] and [Ni(3,3′-Hbpy)Mo4O13(OH)]
- 1 January 2000
- journal article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 14,p. 2255-2257
- https://doi.org/10.1039/b001419m
Abstract
The hydrothermal chemistry of the Ni(II)/molybdate/3,3′-bipyridine system exhibits pronounced pH dependence, such that under basic conditions a 2-D material with embedded clusters [{Ni(3,3′-bpy)2}2Mo4O14] 1 is observed, while under acidic conditions the 2-D bimetallic oxide network of [Ni(3,3′-Hbpy)Mo4O13(OH)] 2 is isolated.Keywords
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