The kinetics of pyrolysis of 1,3,3-trimethylcyclopropene. Evidence for the involvement of alkylidene carbenes in the thermal isomerisation of cyclopropenes
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 421-422
- https://doi.org/10.1039/c39920000421
Abstract
A low yield of 4-methylpent-2-yne in the gas-phase isomerisation of 1,3,3-trimethylcyclopropene is shown to be more consistent with an alkylidene carbene transient than with a, 1,3-biradical intermediate.Keywords
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