Unexpected catalytic and stereoselective hydroarylation of norbornene during the attempted rhodium-catalysed hydroamination of norbornene with aniline or diphenylamine
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1215-1216
- https://doi.org/10.1039/c39920001215
Abstract
The reaction of aniline (or diphenylamine) with norbornene in the presence of a catalytic system generated from [{Rh(PEt3)2Cl}2] and PhNHLi (or Ph2NLi) results in hydroarylation to yield 2-(2-aminophenyl)norbornane [or 2-(2-phenylaminophenyl)norbornane].Keywords
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