Lewis Acid – Base Interactions Between Bis-π-cyclopentadienyl Tungsten and Molybdenum Dihydrides, Cp2MH2, and some Main Group III Moieties
- 1 August 1971
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 49 (15) , 2504-2507
- https://doi.org/10.1139/v71-413
Abstract
Combination of the Lewis bases Cp2MH2 (where M = W or Mo) with the Group III Lewis acids AlR3 (where R = Me, Et, or Ph) and AlMe2H has yielded a series of 1:1 complexes of the type Cp2MH2•AlR3. A number of the complexes undergoes a slow elimination of hydrogen or alkane in benzene solution. Attempts to isolate mixed hydride adducts of the type, Cp2MH2•M′H3 (where M′ = Al or Ga), were unsuccessful.Keywords
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