A model for two-electron mixed valence in metal–metal bonded dirhodium compounds
- 28 January 2005
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 12,p. 1540-1542
- https://doi.org/10.1039/b410003d
Abstract
We propose that two-electron mixed valency in bimetallic complexes possessing three bridging ligands results from a second-order Jahn–Teller instability of the redox-symmetric state.Keywords
This publication has 16 references indexed in Scilit:
- Bis(imino)carbazolide Complexes of Rhodium: Highly Nucleophilic Ligands Exerting a Dramatic Accelerating Effect on MeI Oxidative AdditionOrganometallics, 2004
- Hydrogen Produced from Hydrohalic Acid Solutions by a Two-Electron Mixed-Valence PhotocatalystScience, 2001
- Modern Aspects of the Jahn−Teller Effect Theory and Applications To Molecular ProblemsChemical Reviews, 2001
- Hydrido, Halo, and Hydrido-Halo Complexes of Two-Electron Mixed-Valence Diiridium CoresJournal of the American Chemical Society, 2000
- Four-Electron Photochemistry of Dirhodium Fluorophosphine CompoundsJournal of the American Chemical Society, 1999
- A novel two-electron mixed-valence Ir(II)–Ir(0) complexChemical Communications, 1999
- GoldPublished by Elsevier ,1995
- N,N'-Di-p-tolylformamidinato-bridged mixed-valence iridium(I)-iridium(III) dimers containing a metal-metal dative bond. Synthesis, molecular structure and physicochemical propertiesInorganic Chemistry, 1987
- A second-order Jahn-Teller effect in a tetranuclear metal atom cluster compoundJournal of the American Chemical Society, 1982
- Four- and five-coordinate complexes of rhodium and iridium containing trifluorophosphineInorganic Chemistry, 1971