The total synthesis of optically active annotinine
- 1 February 1969
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 47 (3) , 433-444
- https://doi.org/10.1139/v69-063
Abstract
The total synthesis of the first Lycopodium alkaloid annotinine in the optically active form is described. The key step in this synthesis was the photochemical addition of allene to the tricyclic vinylogous imide (3) which yielded the photoadduct (6).Keywords
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