Synthesis, crystal structure and reactions of zerovalent 16-electron bis-η-cycloheptatrienezirconium
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 850-852
- https://doi.org/10.1039/c39890000850
Abstract
Reduction of ZrCl4 with sodium amalgam in the presence of cycloheptatriene gives [Zr(η-C7H8)2] which is a precursor to the compounds [Zr(η-C7H7)(Me2NCH2CH2NMe2)Cl] and [{Zr(η-C7H7)(thf)}2(µ-Cl)2](thf = tetrahydrofuran).Keywords
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