1,8-Disubstituted Naphthalenes by Directed Metalation and Subsequent Lithium-Manganese Exchange, Including Copper Catalysis
- 1 August 1995
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1995 (08) , 1033-1037
- https://doi.org/10.1055/s-1995-4036
Abstract
Directed lithiation of 1-dimethylamino- and 1-methoxynaphthalene, followed by Li-Mn exchange and reaction with electrophiles, provides regioselective syntheses of previously unknown racemic thioamides 2, 11 and 12, and ketones 5-8.Keywords
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