The First Efficient Hydroaminomethylation with Ammonia: With Dual Metal Catalysts and Two-Phase Catalysis to Primary Amines
- 6 August 1999
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (16) , 2372-2375
- https://doi.org/10.1002/(sici)1521-3773(19990816)38:16<2372::aid-anie2372>3.0.co;2-h
Abstract
Primary and unbranched secondary amines are obtained by the highly selective hydroaminomethylation of olefins with ammonia [Eq. (a)]. The selectivity is readily controlled with a new dual Rh/Ir catalyst in a two‐phase system.Keywords
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