Conjugate Addition of Perfluoroalkyllithiums to α,β-Unsaturated Carbonyl Substrates by Complexation with Aluminum Tris(2,6-diphenylphenoxide)
- 1 January 1994
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1994 (10) , 847-848
- https://doi.org/10.1055/s-1994-23027
Abstract
A variety of perfluoroalkyl groups can be successfully introduced at the β positions of α,β-unsaturated carbonyl substrates using aluminum tris(2,6-diphenylphenoxide)/perfluoroalkyllithium systems, which are very difficult to achieve in organocopper chemistry.Keywords
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