Evidence for a linear sulphurane intermediate in the oxidation of sulphoxide by persulphoxide

1 January 1983

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 21,p. 1203-1204
https://doi.org/10.1039/c39830001203

Abstract

Oxidation of ¹⁸O-labelled [²H₆]dimethyl sulphoxide by dimethyl persulphoxide produced by photosensitized oxygenation of dimethyl sulphide proceeded via a linear sulphurane intermediate.

Keywords

LINEAR SULPHURANE INTERMEDIATE
2H6
OXYGENATION
PROCEEDED
18O
PHOTOSENSITIZED
SULPHIDE

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