The enzymic formation of colneleic acid, a divinyl ether fatty acid: experiments with [(9S)-18O2]hydroperoxyoctadeca-(10E),(12Z)-dienoic acid
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 502-503
- https://doi.org/10.1039/c39870000502
Abstract
Contrary to earlier reports, the oxygen inserted enzymically between carbons 9- and 10- of the C-18 chain in forming colneleic acid originates from 18O2 gas via the 9-hydroperoxide group of linoleic acid; a mechanism is proposed.Keywords
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