Rings and linear polymers formed by addition of silver perchlorate to trans-[Pt(CCR)2(PMe2Ph)2 ] (R = But, H)
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 2,p. 177-178
- https://doi.org/10.1039/a607358a
Abstract
Addition of AgClO 4 to trans-[Pt(CCR) 2 (PMe 2 Ph) 2 ] (R = Bu t , H) gives 1:1 adducts of the general formula trans-[PtAg(ClO 4 )(µ-CCR) 2 (PMe 2 Ph) 2 ] which are cyclic dimers when R = Bu t (ClO 4 - not coordinated) or linear polymers when R = H (ClO 4 - coordinated to silver).Keywords
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