Different bonding modes for 6-(2-thienyl)-2,2′-bipyridine at ruthenium (II); the structural characterisation of [Ru(HL)(HL)Cl][BF4][HL=6-(2-thienyl)-2,2′-bipyridine]
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 913-914
- https://doi.org/10.1039/c39890000913
Abstract
The ligand 6-(2-thienyl)-2,2′-bipyridine (HL) forms ruthenium complexes in which it acts as a terdentate N,N,S-donor, a bidentate N,N-donor, and in a deprotonated form a terdentate N,N,C-donor; the complex [RuCl(HL)2][BF4] has been structurally characterised and shown to contain both N,N,S-- and N,N-bonded ligands.Keywords
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